An indirect method of determination of
excited state equilibria, such as
values, based on
ground state thermodynamics and electronic transition energies. This cycle considers only the
difference in molar
enthalpy change
() of reaction of ground and excited states, neglecting the difference in molar
entropy change of reaction of those states
().Source:
PAC, 1996, 68, 2223
(Glossary of terms used in photochemistry (IUPAC Recommendations 1996))
on page 2243