Quantity the change in which is equal to the heat brought to the system in a reversible
process at constant temperature divided by that temperature. Entropy is zero for an
ideally ordered crystal at 0
. In statistical thermodynamics
where
is the
Boltzmann constant
and
the number of possible arrangements of the system.
Source:
PAC, 1990, 62, 2167
(Glossary of atmospheric chemistry terms (Recommendations 1990))
on page 2187
PAC, 1996, 68, 957
(Glossary of terms in quantities and units in Clinical Chemistry (IUPAC-IFCC Recommendations
1996))
on page 972
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.