Acyl
intermediates include acyl anions, acyl radicals and acyl cations (synonym acylium ions) which
are formally derived from
oxoacidsRkE(=O)l(OH)m
(
l ≠ 0)
by removal of a hydroxyl
cationHO+
, a hydroxyl radical
HO.
or a hydroxyl
anionHO−
, respectively, and replacement analogues of such intermediates. Acyl anions, radicals
and cations can formally be represented by canonical forms having a negative charge,
an unpaired electron or a positive charge on the acid-generating element of the oxoacid.
Acyl anions. E.g.
Acyl radicals. E.g.
Acyl cations. E.g.
Source:
PAC, 1995, 67, 1307
(Glossary of class names of organic compounds and reactivity intermediates based on
structure (IUPAC Recommendations 1995))
on page 1312
PAC, 1993, 65, 1357
(Revised nomenclature for radicals, ions, radical ions and related species (IUPAC
Recommendations 1993))
on page 1357