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puffing

An irreversible expansion of some carbon artifacts during graphitization heat treatment between 1650 and 2700 K.
Note:
Puffing is caused by the release of heteroatoms, for instance sulfur atoms, from the coke in association with specific microstructural rearrangements.
Source:
PAC, 1995, 67, 473 (Recommended terminology for the description of carbon as a solid (IUPAC Recommendations 1995)) on page 502
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: https://doi.org/10.1351/goldbook.P04941.
Original PDF version: http://www.iupac.org/goldbook/P04941.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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