Defined by the equation:
where
is the
chemical potential
of the solute B in a solution containing B and other species. The nature of B must
be clearly stated: it is taken as a group of ions of two kinds carrying an equal number
of positive and negative charges, e.g.
Na+
+
NO3−
or
Ba2+
+
2Cl−
or
2Al3+
+
3SO42−
.
is the total number of ions making up the group i.e. 2, 3 and 5 respectively in the
above examples.
is the
chemical potential of B in its
standard state, usually the hypothetical ideal solution of concentration
and at the same temperature and pressure as the solution under consideration.
Source:
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.