The
amount-of-substance fraction of component in a desolvated state in the amount of component entering the flame.
This quantity is measured in a defined part of the flame, usually the observation
space. Because it varies with height in the flame as a result of progressive
evaporation of
aerosol droplets, it is appropriate to term the expression local. The fraction desolvated
does not account for losses by incomplete
volatilization of the dry
aerosol (which largely depends upon the nature and concentration of the component). Such
losses are described by local fraction volatilized, which usually depends on the solute.
Since
varies markedly with the height in the flame, its observed value represents
an average. Local fraction desolvated depends on the solvent, the temperature of the
flame and the time the component takes to travel from the tip of the burner to the
height in the flame considered.
Source:
PAC, 1986, 58, 1737
(Quantities and units in clinical chemistry: Nebulizer and flame properties in flame
emission and absorption spectrometry (Recommendations 1986))
on page 1740
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.