Of a single pure liquid or solid phase α,
is the work done on the system when a column α
of unit area is split, reversibly, normal to the axis of the column to form two new
surfaces each of unit area in contact with the equilibrium gas phase.
where
is the
surface tension between phase and its equilibrium vapour or a dilute gas phase.
Source:
PAC, 1972, 31, 577
(Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix
II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry)
on page 597