A dual parameter approach to the
correlation analysis of substituent effects, which involves a field constant
(
) and a
resonance constant
(
). The original treatment was modified later. The procedure has been considerably applied,
but also much criticized.
Source:
PAC, 1994, 66, 1077
(Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994))
on page 1170