As applied to
chemical species, the term expresses a thermodynamic property, which is quantitatively measured by
relative molar standard Gibbs energies. A chemical species A is more stable than its
isomer B if
for the (real or hypothetical) reaction
,
under standard conditions. If for the two reactions:
,
P is more stable relative to the product Y than is Q relative to Z. Both in qualitative
and quantitative usage the term stable is therefore always used in reference to some
explicitly stated or implicitly assumed standard. The term should not be used as a
synonym for
unreactive or '
less reactive' since this confuses thermodynamics and kinetics. A relatively more stable chemical
species may be more
reactive than some reference species towards a given reaction partner.
Source:
PAC, 1994, 66, 1077
(Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994))
on page 1166