spin density
The unpaired
electron density
at a position of interest, usually at carbon, in a
radical
It is often measured experimentally by electron
paramagnetic
resonance
[
EPR
,
ESR
(electron spin
resonance
)]
spectroscopy
through
hyperfine coupling
constants of the atom or an attached hydrogen.
See also:
radical centre
Source:
PAC, 1994,
66
, 1077
(Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994))
on page 1166