radiolysis

The cleavage of one or several bonds resulting from exposure to high-energy radiation. The term is also often used loosely to specify the method of irradiation ('pulse radiolysis') used in any radiochemical reaction, not necessarily one involving bond cleavage.
Source:
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1156
PAC, 1994, 66, 2513 (Nomenclature for radioanalytical chemistry (IUPAC Recommendations 1994)) on page 2524