Photoinduced extrusion of carbon monoxide
(
CO).
Notes:
- Typical example is the Norrish Type I photoreaction, in which, after
production of the diradical upon photoinduced α-cleavage,
CO
is eliminated. This reaction has been widely exploited for the production of
radicals in crystals, as well as for the synthesis of cyclic compounds.
- Another example is the photodecarbonylation of alpha-aryl aldehydes.
Source:
PAC, 2007, 79, 293
(Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006))
on page 388