A term sometimes used for a
rate coefficient. For example, if the rate equation is:
the function
![k [A]](../mathml/P04933-1.png)
is the pseudo first-order
rate constant (or first-order
rate coefficient) with respect to B. Similarly,
![k [B]](../mathml/P04933-2.png)
is the pseudo first-order
rate constant (or first-order
rate coefficient) with respect to A. The term pseudo
rate constant is particularly useful when the concentration of one reactant is much greater than
that of another.
Source:
PAC, 1996, 68, 149
(A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC
Recommendations 1996))
on page 178