photoionization detector

Radiation from an ultravioletlamp ionizes certain species in the carrier gas. A potential difference is applied and the resulting ionization current is detected. The detector is only useful for substances with ionization potentials below about . This makes it quite useful for detecting one component of a combined eluent when the other component, for instance nitrogen, has a high ionization potential. The detector has a small linear dynamic range and is capable of detecting substances below .