Laporte rule

This rule states that for monophotonic radiative transitions in centrosymmetric systems, the only non-vanishing electric-dipole transition moments are those which connect an even term (g) with an odd term (u).
Source:
PAC, 1996, 68, 2223 (Glossary of terms used in photochemistry (IUPAC Recommendations 1996)) on page 2251