kinetic control

of product composition
The term characterizes conditions (including reaction times) that lead to reaction products in a proportion governed by the relative rates of the parallel (forward) reactions in which the products are formed, rather than by the respective overall equilibrium constants.
See also: thermodynamic control
Source:
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1133