intramolecular charge transfer, (
ICT
)
Process that changes the overall charge distribution in a molecule.
Note:
For
intramolecular
charge transfer in the
excited state
, several models are discussed in the literature based on the molecular structure of the final state reached upon photo-induced
ICT
:
planar intramolecular charge transfer
(
PICT
) or
twisted intramolecular charge transfer
(
TICT
). For example, an
ICT
has been proposed to be responsible for the strongly
Stokes-shifted
additional
fluorescence
band in fluorescent molecules with two
fluorescence
bands (
dual fluorescent
molecules).
Source:
PAC, 2007,
79
, 293
(Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006))
on page 357