A
molecular entity with a
lifetime appreciably longer than a molecular vibration (corresponding to a local potential
energy minimum of depth greater than
)
that is formed (directly or indirectly) from the reactants and reacts further to give
(either directly or indirectly) the products of a
chemical reaction; also the corresponding
chemical species.
Source:
PAC, 1994, 66, 1077
(Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994))
on page 1126
See also:
PAC, 1996, 68, 149
(A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC
Recommendations 1996))
on page 170