heterogeneous diffusion rate constant
in electrochemistry
Defined by the equation:
where the
limiting current
is assumed to be due to the
diffusion
species of concentration
and of
diffusion coefficient
.
is the
charge number of the cell reaction
written so that the
stoichiometric
coefficient
of this species is unity.
is usually taken as the geometric area of the electrode, and
is the
Faraday constant
.
Source:
PAC, 1974,
37
, 499
(Electrochemical nomenclature)
on page 513