This quantity is often calculated directly from experimental measurements (e.g. determination
of concentrations by
electrode potential measurements, or
), although its significance may not always have been recognized. The problem is that
the average value of a
variable (such as
) that is a function of concentration is not the same as the value of the function
at the average concentration. In the case of electrode potentials, the average potential
is equivalent to the geometric mean concentration. The correct procedure is to transform
to units of concentration before averaging. There is one notable case where the geometric
mean is appropriate, namely, when the analyte itself is distributed in a log-normal
fashion, as in certain environmental and geological samples.