extrusion transformation

A transformation in which an atom or group Y connected to two other atoms or groups X and Z is lost from a molecule, leading to a product in which X is bonded to Z, e.g.
E02311-1
or
E02311-2
The reverse of an extrusion is called insertion.
See: cheletropic reaction
Source:
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1114