The ratio of a dimensional characteristic of a macromolecule in a given solvent at
a given temperature to the same dimensional characteristic in the
state at the same temperature. The most frequently used expansion factors are: expansion
factor of the mean-square end-to-end distance,
;
expansion factor of the
radius of gyration;
viscosity expansion factor
where
and
are the intrinsic
viscosity in a given solvent and in the
state at the same temperature, respectively. Expansion factors defined by different
dimensional characteristics are not exactly equal, nor need they have a constant ratio
as a function of
relative molecular mass.
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