exchange current

of an electrode reaction
The common value I 0 of the anodic and cathodic partial currents when the reaction is at equilibrium
I 0 = I a = − I c
For an electrode at equilibrium at which only one reaction is significant I = 0. When more than one reaction is significant at a given electrode, subscripts to I 0 may be used to distinguish exchange currents. I is not usually zero when only one of these reactions is at equilibrium.
Source:
PAC, 1974, 37, 499 (Electrochemical nomenclature) on page 513