There is a relatively small range of concentrations separating the limit below which
virtually no
micelles are detected and the limit above which virtually all additional surfactant molecules
form micelles. Many properties of surfactant solutions, if plotted against the concentration,
appear to change at a different rate above and below this range. By extrapolating
the loci of such a property above and below this range until they intersect, a value
may be obtained known as the critical micellization concentration (critical
micelle concentration), symbol
, abbreviation
cmc (or
c.m.c.). As values obtained using different properties are not quite identical, the method
by which the
cmc is determined should be clearly stated.
Source:
PAC, 1994, 66, 1077
(Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994))
on page 1101