chemi-ionization

in mass spectrometry
This refers to a process whereby gaseous molecules are ionized when they interact with other internally excited gaseous molecules or molecular moieties. Chemi-ionization and chemical ionization are two terms which should not be used interchangeably.
See also: associative ionization, chemical ionization
Source:
PAC, 1991, 63, 1541 (Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1547
Orange Book, p. 204