Generic name for anions containing an even number of electrons and having an unshared
pair of electrons on a tervalent carbon atom (e.g.
Cl3C−
or
HC≡C−
) or — if the ion is mesomeric (see
mesomerism) — having at least one significant
contributing structure with an unshared pair of electrons on a tervalent carbon atom, for example:
Source:
PAC, 1994, 66, 1077
(Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994))
on page 1092
See also:
PAC, 1995, 67, 1307
(Glossary of class names of organic compounds and reactivity intermediates based on
structure (IUPAC Recommendations 1995))
on page 1324