A calibration of a
size-exclusion chromatography
set-up based on the finding that the retention volume of a molecular or particulate
species is a single-valued function of an appropriate size parameter of this molecule
or particle, irrespective of its chemical nature and structure. The product of the
intrinsic viscosity and molar mass,
,
has been widely used as the size parameter.
Source:
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.