This occurs when the specifically adsorbed amount of charge in the
inner Helmholtz plane is higher than the charge on the metal phase, taken with the reverse sign.
Source:
PAC, 1986, 58, 437
(Interphases in systems of conducting phases (Recommendations 1985))
on page 448
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.
