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preferential sorption

Synonym: selective sorption in polymer chemistry

in polymers
An equilibrium phenomenon, operative in polymer solutions in multicomponent solvents and in polymer networks swollen by multicomponent solvents, that produces differences in solvent composition in the polymer-containing region and in the pure solvent which is in thermodynamic equilibrium with that region. Synonymous with selective sorption.
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: https://doi.org/10.1351/goldbook.P04812.
Original PDF version: http://www.iupac.org/goldbook/P04812.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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