That value of pH in an aqueous phase at which the distribution ratio is unity at equilibrium.
50% of the solute is extracted
(
) only when the phase ratio is unity.
Source:
PAC, 1993, 65, 2373
(Nomenclature for liquid-liquid distribution (solvent extraction) (IUPAC Recommendations
1993))
on page 2385
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.
