Peak widths represent retention dimensions (time or volume) parallel to the baseline.
If the baseline is not parallel to the axis representing time or volume, then the
peak widths are to be drawn parallel to this axis. Three peak-width values are commonly
used in
chromatography. Peak width at base
(
)
is the segment of the peak base intercepted by the tangents drawn to the inflection
points on either side of the peak. Peak width at half height
(
) is the length of the line parallel to the peak base at 50% of the peak height that
terminates at the intersection with the two limbs of the peak. Peak width at inflection
points
(
)
is the length of the line drawn between the inflection points parallel to the peak
base. The peak width at base may be called the '
base width'. However, the peak width at half height must never be called the '
half width' because that has a completely different meaning. Also, the symbol
should never be used instead of
.
Source:
PAC, 1993, 65, 819
(Nomenclature for chromatography (IUPAC Recommendations 1993))
on page 836
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.
in chromatography
