A term used to characterize the degree of
oxidation (or reduction) in atoms, molecules and ions. It can be applied to an atom in a molecule
or an ion which has a high
oxidation state. An element or atom in a compound can be oxidized by reaction with oxygen, while
it can be reduced by reaction with hydrogen. An oxidized species may be formed also
through the loss of electrons (either to the positive electrode in a cell, or through
transfer to another atom or group of atoms). For example, the sulfur in
H2S is reduced sulfur relative to elementary sulfur, while
SO2 and
SO3 are oxidized. Metallic iron
(
Fe) is a reduced state of iron, while the
Fe2+ ion (ferrous ion) and
Fe3+ ion (ferric ion) are oxidized states of iron.
Fe3+ is in a higher
oxidation state than
Fe2+
which is in a higher
oxidation state than
Fe.
Source:
PAC, 1990, 62, 2167
(Glossary of atmospheric chemistry terms (Recommendations 1990))
on page 2204
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.