oscillator strength, $f i j$

Measure for integrated intensity of electronic transitions and related to the Einstein transition probability coefficient $A i j$ by:

$f i j = 1.4992 × 10 −14 A i j s −1 ( λ nm ) 2$ ,

where $λ$ is the transition wavelength. There are, however, differing uses of $f$ .

Source:

Green Book, 2nd ed., p. 33

See also: PAC, 1996, 68, 2223 (Glossary of terms used in photochemistry (IUPAC Recommendations 1996)) on page 2257

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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.

Last update: 2014-02-24; version: 2.3.3.

DOI of this term: https://doi.org/10.1351/goldbook.O04339.

Original PDF version: http://www.iupac.org/goldbook/O04339.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.

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