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non-ideal, non-linear chromatography

Chromatographic process, where both isotherm curvature and other peak-broadening processes (such as diffusion) contribute to the peak shape.
Note:
This case comprises most peaks in common practice that are characterised as 'tailing' or 'fronting'.
Source:
PAC, 1996, 68, 1591 (Nomenclature for non-linear chromatography (IUPAC Recommendations 1996)) on page 1594
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: https://doi.org/10.1351/goldbook.NT06945.
Original PDF version: http://www.iupac.org/goldbook/NT06945.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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