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Norrish Type II photoreaction

Intramolecularabstraction of a γ-hydrogen by an excited carbonyl compound to produce a 1,4-diradical as a primary photoproduct.
Note:
An example is:
N04218
Source:
PAC, 2007, 79, 293 (Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)) on page 375
InChI=1/C7H14O/c1-6(2)4-5-7(3)8/h6H,4-5H2,1-3H3
InChI=1/C7H14O/c1-6(2)4-5-7(3)8/h8H,4-5H2,1-3H3
FFWSICBKRCICMR-UHFFFAOYAQ
SVDMGEMHANNXSA-UHFFFAOYAP
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: https://doi.org/10.1351/goldbook.N04218.
Original PDF version: http://www.iupac.org/goldbook/N04218.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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