mixed potential

The value of the potential of a given electrode with respect to a suitable reference electrode when appreciable contributions to the total anodic and/or cathodic partial currents are made by species belonging to two or more different couples, but the total current is zero, i.e.

$I = ∑ i I i = 0 ( I i ≠ 0 )$

where $I i$ is the partial current of reaction $i$

$I i = I i , a + I i , c$

Source:

PAC, 1974, 37, 499 (Electrochemical nomenclature) on page 513

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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.

Last update: 2014-02-24; version: 2.3.3.

DOI of this term: https://doi.org/10.1351/goldbook.M03944.

Original PDF version: http://www.iupac.org/goldbook/M03944.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.

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