A development of
transition-state theory in which the
dividing surface is varied so as to minimize the rate calculated for a fixed energy. The rate expressions
obtained in a microcanonical treatment can be integrated over the energy, taking into
account the statistical distribution over energy states, so as to give the canonical,
or thermal, rates.
Source:
PAC, 1996, 68, 149
(A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC
Recommendations 1996))
on page 173
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.
