mass-transfer-controlled electrolyte rate constant

In controlled-potential coulometry and related techniques, the empirically evaluated constant of proportionality defined by the equation

$s B = − 1 c B d c B d t$

where $c B$ is the bulk concentration of the substance B, and $d c B d t$ is the rate of change of that concentration, resulting from the consumption of B by reduction or oxidation at the working electrode.

Source:

PAC, 1985, 57, 1491 (Recommended terms, symbols, and definitions for electroanalytical chemistry (Recommendations 1985)) on page 1501

Interactive Link Maps
First Level	Second Level	Third Level

Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.

Last update: 2014-02-24; version: 2.3.3.

DOI of this term: https://doi.org/10.1351/goldbook.M03755.

Original PDF version: http://www.iupac.org/goldbook/M03755.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.

Current PDF version | Version for print | History of this term

PREVIOUS	M03755	NEXT
mass-to-charge ratio, $m z$ in mass spectrometry		massic