A
diffusionless transition (first studied in the steel alloy, Martensite), at constant composition, generated
by coordinated atomic, ionic or molecular displacements over distances smaller than
interatomic distances in the parent phase. The cooperative rearrangements of the crystal
structure generally take place progressively by the movement of a two-dimensional
interface through the solid. Examples: The face-centred-cubic to body-centred-tetragonal transition
of iron containing some carbon; the transition of tetragonal
ZrO2
to monoclinic
ZrO2
.
Source:
PAC, 1994, 66, 577
(Definitions of terms relating to phase transitions of the solid state (IUPAC Recommendations
1994))
on page 585
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.