NMR method for determining kinetics of chemical exchange by perturbing the magnetization
of nuclei in a particular site or sites and following the rate at which magnetic equilibrium
is restored. The most common perturbations are
saturation and
inversion, and the corresponding techniques are often called '
saturation transfer' and '
selective inversion-recovery'.
Source:
PAC, 1994, 66, 1077
(Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994))
on page 1137
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.
