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ligand field

Ligand field theory is a modified crystal field theory that assigns certain parameters as variables rather than taking them as equal to the values found for free ions, thereby taking into account the potential covalent character of the metal-ligand bond.
Source:
PAC, 1997, 69, 1251 (Glossary of terms used in bioinorganic chemistry (IUPAC Recommendations 1997)) on page 1283
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: https://doi.org/10.1351/goldbook.LT06764.
Original PDF version: http://www.iupac.org/goldbook/LT06764.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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