A chemical reaction, the principal product of which is
isomeric with the principal reactant. An
intramolecular isomerization that involves the breaking or making of bonds is a special case of
a
molecular rearrangement. Isomerization does not necessarily imply
molecular rearrangement (e.g. in the case of the interconversion of conformational isomers).
Source:
PAC, 1994, 66, 1077
(Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994))
on page 1129
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.
