An affix giving a topological indication of the bonding between a π-electron ligand
and the
central atom in a
coordination entity. A right superscript numerical index indicates the number of ligating atoms in the
π-electron system of the ligand which bind to the
central atom.
Examples:
- [Fe(CO)3(C4H6SO)],
tricarbonyl(η2-dihydrothiophene 1-oxide-κO)iron.
- [Cr(CO)4(C4H6)],
tetracarbonyl(η4-2-methylene-1,3-propanediyl)chromium.
Source:
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.