A cylindrical
cathode with a window, an axial wire
anode and an ionizable gas. The gas may be continuously replenished giving a flow-through
detector or the detector may be sealed. Following an original ionizing event, electron
multiplication occurs through a process of gas amplification in the high electric
field surrounding the
anode wire. The gain of this process is defined as the number of electrons collected on
the
anode wire for each primary electron produced. For X-rays having energies higher than the
excitation potential of the detector gas, the
spectral responsivity function has a second peak in addition to the main peak that is called the escape peak. The
escape peak has a mean pulse height proportional to the difference between the photon
energy of the incident X-rays and of the spectral characteristic line of the detector
gas. A
quenching gas, a molecular gas, is added to the detector gas in order to neutralize the detector
gas ions and to absorb secondary electrons as well as UV radiation resulting from
neutralization of detector gas ions. According to the potential applied to the
anode, the detector can work as an
ionization chamber,
proportional counter, or
Geiger counter.
Source:
PAC, 1995, 67, 1745
(Nomenclature, symbols, units and their usage in spectrochemical analysis-XI. Detection
of radiation (IUPAC Recommendations 1995))
on page 1753
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.