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flat band potential (at a semiconductor/solution interphase)

If effects of surface states are negligible, Δ φ sc, the potential drop associated with the space charge in the semiconductor, vanishes as the charge on the semiconductor becomes zero. The potential of the semiconductor corresponding to this condition is the flat band potential, which plays the same role as the potential of zero charge for metals.
Source:
PAC, 1986, 58, 437 (Interphases in systems of conducting phases (Recommendations 1985)) on page 444
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: https://doi.org/10.1351/goldbook.F02421.
Original PDF version: http://www.iupac.org/goldbook/F02421.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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