Esin and Markov coefficient

The left-hand side of one of the various cross-differential relationships that can be obtained from the Gibbs adsorption equation when only one chemical potential( $μ$ ) is considered as variable, viz.

$( ∂ E ∂ μ ) T , p , σ = − ( ∂ Γ ∂ σ ) T , p , μ$

where $E$ is the potential difference, $T$ is the temperature, $p$ is the pressure, $Γ$ is the surface excess and $σ$ is the charge density.

Source:

PAC, 1986, 58, 437 (Interphases in systems of conducting phases (Recommendations 1985)) on page 446

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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.

Last update: 2014-02-24; version: 2.3.3.

DOI of this term: https://doi.org/10.1351/goldbook.E02218.

Original PDF version: http://www.iupac.org/goldbook/E02218.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.

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