If the charging current is negligible, in the case of a single
electrode reaction, the electrode
current density (
) of the
electric current flowing through the electrode is related to the flux density of a species
B by the equation:
where
is the normal component of the vector
at the electrode-solution
interface,
is the
charge number of the
electrode reaction
and
is the
stoichiometric number of species
B.
The ratio
is to be taken as positive if the species
B is consumed in a cathodic reaction or produced in an anodic reaction. Otherwise it
is to be taken as negative. With the convention that the normal distance vector points
into the electrolytic solution, a cathodic current is then negative, an anodic current
positive.
Source:
PAC, 1981, 53, 1827
(Nomenclature for transport phenomena in electrolytic systems)
on page 1835
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.