An analytical method in which a reactant is injected into a calorimetric vessel containing
another
reagent. The
enthalpy change of the ensuing reaction is measured and directly related to the amount of
the limiting
reagent (usually the analyte). If the experiment determines information other than amounts
of analytes, an acceptable synonym is
batch injection calorimetry. Other terms which have been used in the literature but are not recommended include
the
concentration thermometric technique and the
direct thermometric method.
Source:
PAC, 1994, 66, 2487
(Nomenclature of thermometric and enthalpimetric methods in chemical analysis (IUPAC
Recommendations 1994))
on page 2490
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.
