A transition in which the crystal structure is dilated (or compressed) along one (or
more) crystallographic direction(s) while the symmetry about that direction is retained.
Examples:
-
The transition of a CsCl-type structure to a rock salt structure in which dilation occurs along the three-fold axis.
-
The transition at
in quenched NiS
in which volume expansion occurs without change of symmetry on going from a metallic
state (
) to a semiconducting state (
).
Source:
PAC, 1994, 66, 577
(Definitions of terms relating to phase transitions of the solid state (IUPAC Recommendations
1994))
on page 581
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by
A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997).
XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic,
J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
https://doi.org/10.1351/goldbook.
