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deliquescence

The process that occurs when the vapour pressure of the saturated aqueous solution of a substance is less than the vapour pressure of water in the ambient air. When water vapour is collected by the pure solid compound, a mixture of the solid and liquid or an aqueous solution of the compound forms until the substance is dissolved and is in equilibrium with its environment; at this time the vapour pressure of water over the aqueous solution will equal the partial pressure of water in the atmosphere in contact with it. A crystalline saltaerosol particle will deliquesce in the atmosphere when the relative humidity surpasses a characteristic value, the so-called deliquescence point.
Source:
PAC, 1990, 62, 2167 (Glossary of atmospheric chemistry terms (Recommendations 1990)) on page 2183
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: https://doi.org/10.1351/goldbook.D01582.
Original PDF version: http://www.iupac.org/goldbook/D01582.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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